Ontology highlight
ABSTRACT:
SUBMITTER: Aupic C
PROVIDER: S-EPMC6611065 | biostudies-literature | 2019 Jul
REPOSITORIES: biostudies-literature
Chemical science 20190524 26
Stereogenic main group elements are clearly generating interest in the enantioselective catalysis field. Surprisingly, while chiral organoboron reagents are very useful in stereoselective transformations, few scaffolds stereogenic at boron and configurationally stable have been reported to date. Herein, we describe an original library of chiral NHC-boranes, stereogenic at the boron atom, that has been prepared in only a few steps and in good yields (up to 93%). Key steps involve a chlorination/a ...[more]