Dataset Information

Neutralizing the Charge Imbalance Problem in Eu³⁺-Activated BaAl₂O₄ Nanophosphors: Theoretical Insights and Experimental Validation Considering K⁺ Codoping.

ABSTRACT: In recent years, rare-earth-doped nanophosphors have attracted great attention in the field of luminescent materials for advanced solid-state lighting and high-resolution display applications. However, the low efficiency of concurrent red phosphors creates a major bottleneck for easy commercialization of these devices. In this work, intense red-light-emitting K⁺-codoped BaAl₂O₄:Eu³⁺ nanophosphors having an average crystallite size of 54 nm were synthesized via a modified sol-gel method. The derived nanophosphors exhibit strong red emission produced by the ⁵D₀ ? ⁷F _J (J = 0, 1, 2, 3, 4) transitions of Eu³⁺ upon UV and low-voltage electron beam excitation. Comparative photoluminescence (PL) analysis is executed for Eu³⁺-activated and K⁺-coactivated BaAl₂O₄:Eu³⁺ nanophosphors, demonstrating remarkable enhancement in PL intensity as well as thermal stability due to K⁺ codoping. The origin of this PL enhancement is also analyzed from first-principles calculations using density functional theory. Achievement of charge compensation with the addition of a K⁺ coactivator plays an important role in increasing the radiative lifetime and color purity of the codoped nanophosphors. Obtained results substantially approve the promising prospects of this nanophosphor in the promptly growing field of solid-state lighting and field emission display devices.

SUBMITTER: Chatterjee R

PROVIDER: S-EPMC6641287 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature

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Publications

Neutralizing the Charge Imbalance Problem in Eu3+-Activated BaAl2O4 Nanophosphors: Theoretical Insights and Experimental Validation Considering K+ Codoping.

Chatterjee Rituparna R Saha Subhajit S Sen Dipayan D Panigrahi Karamjyoti K Ghorai Uttam Kumar UK Das Gopes Chandra GC Chattopadhyay Kalyan Kumar KK

ACS omega 20180122 1

In recent years, rare-earth-doped nanophosphors have attracted great attention in the field of luminescent materials for advanced solid-state lighting and high-resolution display applications. However, the low efficiency of concurrent red phosphors creates a major bottleneck for easy commercialization of these devices. In this work, intense red-light-emitting K+-codoped BaAl2O4:Eu3+ nanophosphors having an average crystallite size of 54 nm were synthes ...[more]

PMID: 31457929

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Project description:Engineering a single material with multidirectional applications is crucial for improving productivity, low cost, flexibility, least power consumption, etc. To achieve these requirements, novel design structures and high-performance materials are in urgent need. Lanthanide-doped nanophosphors have the greatest strengths and ability in order to tune their applications in various dimensions. However, applications of nanophosphor in latent fingerprints visualization, anti-counterfeiting, and luminescent gels/films are still in their infancy. This study demonstrated a simple strategy to enhance the luminescence of Tb3+ (1-11 mol %) doped La2Zr2O7 nanophosphors by conjugating various fluxes via a simple solution combustion route. The photoluminescence emission spectra reveal intense peaks at ~ 491, 546, 587, and 622 nm, which arises from 5D4 → 7FJ (J = 6, 5, 4, 3) transitions of Tb3+ ions, respectively. The highest emission intensity was achieved in the NH4Cl flux assisted nanophosphor as compared to NaBr and NH4F assisted samples. The colorimetric images of fingerprints visualized using the optimized nanophosphor on forensic related surfaces exhibit level -III ridge details, including sweat pores, the width of the ridges, bifurcation angle, and the successive distance between sweat pores, etc. These results are decisive parameters that clearly support the statement "no two persons have ever been found to have the same fingerprints". The anti-counterfeiting security ink was formulated using optimized nanophosphor and various patterns were designed by simple screen printing and dip pen technologies. The encoded information was decrypted only under ultraviolet 254 nm light. All the designed patterns are exhibit not just what it looks/feel like and how better it works. As a synergetic contribution of enhanced luminescence of the prepared nanophosphor, the green-emissive films were fabricated, which display excellent flexibility, uniformity, and transparency in the normal and ultraviolet 254 nm light illumination. The aforementioned results revealed that the prepared NH4Cl flux-assisted La2Zr2O7: Tb3+(7 mol %) NPs are considered to be the best candidate for multi-dimensional applications.

Dataset Information

Neutralizing the Charge Imbalance Problem in Eu³⁺-Activated BaAl₂O₄ Nanophosphors: Theoretical Insights and Experimental Validation Considering K⁺ Codoping.

Publications

Neutralizing the Charge Imbalance Problem in Eu<sup>3+</sup>-Activated BaAl<sub>2</sub>O<sub>4</sub> Nanophosphors: Theoretical Insights and Experimental Validation Considering K<sup>+</sup> Codoping.

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