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Self-Healing Hydrogel from a Dipeptide and HCl Sensing.

ABSTRACT: Ordered self-assembly of small organic molecules may induce novel properties in a supramolecular arrangement and can act as advance functional materials. This paper discusses the development of a new stimuli-responsive dipeptide hydrogelator containing l-phenylalanine and ?-aminoisobutyric acid (Aib). The dipeptide Boc-Phe-Aib-OH, on addition with three equivalent of sodium hydroxide and water, transformed into a robust hydrogel. The transparent hydrogel is self-healing in nature. The instant gelation is highly selective toward sodium hydroxide and does not need any sonication or heating-cooling cycle. The thixotropic nature of the gel has been confirmed by rheological step-strain experiments at room temperature. Moreover, in the oil-water mixture, the compound exhibits phase-selective gelation. When the gel cylinder is cut into pieces, it does not conduct electricity, but once self-healing occurs, it conducts electricity. The diffusion of rhodamine 6G through the hydrogel indicates the dynamic nature. The hydrogel is highly sensitive toward HCl, that is, in the presence of HCl vapor, the gel becomes deformed.

SUBMITTER: Nandi SK

PROVIDER: S-EPMC6641447 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

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Self-Healing Hydrogel from a Dipeptide and HCl Sensing.

Nandi Sujay Kumar SK Maji Krishnendu K Haldar Debasish D

ACS omega 20180403 4

Ordered self-assembly of small organic molecules may induce novel properties in a supramolecular arrangement and can act as advance functional materials. This paper discusses the development of a new stimuli-responsive dipeptide hydrogelator containing l-phenylalanine and α-aminoisobutyric acid (Aib). The dipeptide Boc-Phe-Aib-OH, on addition with three equivalent of sodium hydroxide and water, transformed into a robust hydrogel. The transparent hydrogel is self-healing in nature. The instant ge ...[more]

PMID: 31458618

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Project description:In this study, a self-healing hydrogel was prepared that is transparent to visible (Vis) light while absorbing ultraviolet (UV), infrared (IR), and microwave. The optothermal features of the hydrogel were explored by monitoring temperature using an IR thermometer under an IR source. The hydrogel was synthesized using sodium tetraborate decahydrate (borax) and polyvinyl alcohol (PVA) as raw materials based on a facile thermal route. More significantly, graphene oxide (GO) and graphite-like carbon nitride (g-C3N4) nanostructures as well as carbon microsphere (CMS) were applied as guests to more dissect their influence on the microwave and optical characteristics. The morphology of the fillers was evaluated using field emission scanning electron microscopy (FE-SEM). Fourier transform infrared (FTIR) attested that the chemical functional groups of the hydrogel have been formed and the result of diffuse reflection spectroscopy (DRS) confirmed that the hydrogel absorbs UV while is transparent in Vis light. The achieved result implied that the hydrogel acts as an essential IR absorber due to its functional groups desirable for energy efficiency and harvesting. Interestingly, the achieved results have testified that the self-healing hydrogels had the proper self-healing efficiency and self-healing time. Eventually, microwave absorbing properties and shielding efficiency of the hydrogel, hydrogel/GO, g-C3N4, or CMS were investigated, demonstrating the salient microwave characteristics, originated from the established ionic conductive networks and dipole polarizations. The efficient bandwidth of the hydrogel was as wide as 3.5 GHz with a thickness of 0.65 mm meanwhile its maximum reflection loss was 75.10 dB at 14.50 GHz with 4.55 mm in thickness. Particularly, the hydrogel illustrated total shielding efficiency (SET) > 10 dB from 1.19 to 18 and > 20 dB from 4.37 to 18 GHz with 10.00 mm in thickness. The results open new windows toward improving the shielding and energy efficiency using practical ways.

Dataset Information

Self-Healing Hydrogel from a Dipeptide and HCl Sensing.

Publications

Self-Healing Hydrogel from a Dipeptide and HCl Sensing.

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