Amide-Functionalized Chalcogen-Bridged Flexible Tetranuclear Rhenacycles: Synthesis, Characterization, Solvent Effect on the Structure, and Guest Binding.

ABSTRACT: The synthesis of flexible rhenium(I)-based amide-functionalized chalcogen-bridged tetranuclear metallacycles of general formula [{(CO)₃Re(?-ER)₂Re(CO)₃}₂(?-L)₂] (1-8) was achieved by treating rhenium carbonyl with dialkyl/diaryl chalcogenide (RE-ER; E = S and Se) in the presence of ditopic flexible or semiflexible pyridyl ligand with amide functionality (L = N,N'-bis(4-pyridylcarboxamide)-1,2-ethane (bpce) and N,N'-bis(4-(4-pyridylcarboxamide)phenyl)methane (bpcpm)). Compounds 1-8 were formed by multicomponent self-assembly under one-pot reaction conditions via oxidative addition of dialkyl/diaryl chalcogenide to rhenium carbonyl with pyridyl ligands. The resultant metallacyclophanes were characterized using elemental analyses, infrared, ultraviolet-visible, and NMR spectroscopic techniques. Metallacyclophanes 1-3 and 7 were structurally characterized by single-crystal X-ray diffraction methods. The solvent-induced structural change of flexible tetranuclear metallacyclophane 2 was demonstrated by crystallizing 2 in dichloroethane and dimethylformamide. Molecular recognition capabilities of 2 and 7 were studied with few aromatic compounds containing ethereal linkages.

SUBMITTER: Karthikeyan M 

PROVIDER: S-EPMC6641653 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature