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Unique Design of Porous Organic Framework Showing Efficiency toward Removal of Toxicants.

ABSTRACT: This report deligates about the creation of porous polymeric organic framework (POF) from dialkynes and poly(alkyne) with their discovery as an efficient set of purifier. POF showed efficient physisorption for dyes-fluorescein and rhodamine B. The material POF selectively released rhodamine B and not fluorescein. The material was recyclable over number of cycles during the adsorption-release cycle. Moreover, the thiol-functionalized POF expectedly showed chemisorption for mercury. Therefore, the prime attractive cause for such a material is its ability to recycle as well as its thiol functionalization toward the removal of heavy metal such as mercury.

SUBMITTER: Kumar R

PROVIDER: S-EPMC6641704 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature

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Unique Design of Porous Organic Framework Showing Efficiency toward Removal of Toxicants.

Kumar Rajan R Shunmugam Raja R

ACS omega 20170801 8

This report deligates about the creation of porous polymeric organic framework (POF) from dialkynes and poly(alkyne) with their discovery as an efficient set of purifier. POF showed efficient physisorption for dyes-fluorescein and rhodamine B. The material POF selectively released rhodamine B and not fluorescein. The material was recyclable over number of cycles during the adsorption-release cycle. Moreover, the thiol-functionalized POF expectedly showed chemisorption for mercury. Therefore, the ...[more]

PMID: 31457711

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Project description:In this study, a minimum-run resolution IV and central composite design have been developed to optimize tetracycline removal efficiency over mesoporous carbon derived from the metal-organic framework MIL-53 (Fe) as a self-sacrificial template. Firstly, minimum-run resolution IV, powered by the Design-Expert program, was used as an efficient and reliable screening study for investigating a set of seven factors, these were: tetracycline concentration (A: 5-15 mg/g), dose of mesoporous carbons (MPC) (B: 0.05-0.15 g/L), initial pH level (C: 2-10), contact time (D: 1-3 h), temperature (E: 20-40 °C), shaking speed (F: 150-250 rpm), and Na+ ionic strength (G: 10-90 mM) at both low (-1) and high (+1) levels, for investigation of the data ranges. The 20-trial model was analyzed and assessed by Analysis of Variance (ANOVA) data, and diagnostic plots (e.g., the Pareto chart, and half-normal and normal probability plots). Based on minimum-run resolution IV, three factors, including tetracycline concentration (A), dose of MPC (B), and initial pH (C), were selected to carry out the optimization study using a central composite design. The proposed quadratic model was found to be statistically significant at the 95% confidence level due to a low P-value (<0.05), high R2 (0.9078), and the AP ratio (11.4), along with an abundance of diagnostic plots (3D response surfaces, Cook's distance, Box-Cox, DFFITS, Leverage versus run, residuals versus runs, and actual versus predicted). Under response surface methodology-optimized conditions (e.g., tetracycline concentration of 1.9 mg/g, MPC dose of 0.15 g/L, and pH level of 3.9), the highest tetracycline removal efficiency via confirmation tests reached up to 98.0%-99.7%. Also, kinetic intraparticle diffusion and isotherm models were systematically studied to interpret how tetracycline molecules were absorbed on an MPC structure. In particular, the adsorption mechanisms including "electrostatic attraction" and "π-π interaction" were proposed.

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Unique Design of Porous Organic Framework Showing Efficiency toward Removal of Toxicants.

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Unique Design of Porous Organic Framework Showing Efficiency toward Removal of Toxicants.

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