Ontology highlight
ABSTRACT:
SUBMITTER: Martin HJ
PROVIDER: S-EPMC6644359 | biostudies-literature | 2018 Aug
REPOSITORIES: biostudies-literature
Martin Harry J HJ Pfeiffer Constance R CR Stephen Davies E E Davis Adrienne L AL Lewis William W Champness Neil R NR
ACS omega 20180808 8
The role of intramolecular hydrogen-bonding interactions upon the nuclearity of palladium tiara-like complexes is reported herein. The synthesis of three palladium tiaras is described with three related thiolate ligands that vary in their hydrogen-bonding capability, amide vs ester for <i>N</i>-acetylcysteamine (tiara <b>1</b>) vs 2-mercaptoethyl acetate (tiara <b>2</b>) or ethyl thioglycolate (tiara <b>3</b>), and in the relative position of the ester group, 2-mercaptoethyl acetate (<b>2</b>) o ...[more]