Synthesis and Characterization of Two-Dimensional Transition Metal Dichalcogenide Magnetic MoS₂@Fe₃O₄ Nanoparticles for Adsorption of Cr(VI)/Cr(III).

ABSTRACT: Recently, two-dimensional transition metal dichalcogenides (TMDs) have received tremendous attention in many fields including environmental remediation. Magnetic nanoparticles (Fe₃O₄NPs) decorated with MoS₂ (MoS₂@Fe₃O₄NPs) have been synthesized via a new one-step synthesis route and utilized as an efficient adsorbent for removal of Cr(VI)/Cr(III) from aqueous solutions. The obtained MoS₂@Fe₃O₄NPs with numerous surface hydroxyl groups show uniform size and shape, excellent water-dispersibility, and superior magnetic property to enhance the adsorption. The physicochemical properties of the adsorbent prior to and after adsorption of Cr(VI)/Cr(III) were extensively characterized using several advanced instrumental techniques.The adsorption of Cr(VI)/Cr(III) on MoS₂@Fe₃O₄NPs was performed under batch conditions aiming at identification of optimal contact time, pH value of chromium solution, and influence of the presence of competitive ions. This study was supported by modeling of adsorption equilibrium and kinetics by using empirical equations.

SUBMITTER: Krishna Kumar AS 

PROVIDER: S-EPMC6644607 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature