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Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates.

ABSTRACT: A novel method has been developed for the synthesis of highly substituted enecarbamates and trisubstituted alkenes from arylhydrazine-1,2-dicarboxylates and 1,2-disubstituted alkynes through a sequential C-C and C-N bond formation. It is entirely a new strategy to produce enecarbamates in a highly regio- and stereoselective manner.

SUBMITTER: Reddy CR

PROVIDER: S-EPMC6644781 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature

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Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates.

Reddy Chatrala Ravikumar CR Sridhar Balasubramanian B V Subba Reddy Basi B

ACS omega 20180822 8

A novel method has been developed for the synthesis of highly substituted enecarbamates and trisubstituted alkenes from arylhydrazine-1,2-dicarboxylates and 1,2-disubstituted alkynes through a sequential C-C and C-N bond formation. It is entirely a new strategy to produce enecarbamates in a highly regio- and stereoselective manner. ...[more]

PMID: 31459104

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