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Oxidized Carbon Black as an Activator of Transesterification Reactions under Solvent-Free Conditions.

ABSTRACT: A metal-free procedure for oxidation of carbon black (CB), under mild and ecofriendly conditions, is described. The procedure, based on 5/1 w/w H₂O₂/H₂SO₄, when applied to high-surface-area CB, leads to oxidation contents (O/C = 0.66) comparable to those obtained for graphite with the more aggressive and metal-based Hummers method (O/C 0.63). Oxidized nanocarbons are able to activate transesterification reactions under solvent-free conditions. Activation of transesterification reactions is much more effective by oxidized CB than by graphene oxide.

SUBMITTER: Acocella MR

PROVIDER: S-EPMC6644938 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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Oxidized Carbon Black as an Activator of Transesterification Reactions under Solvent-Free Conditions.

Acocella Maria Rosaria MR Maggio Mario M Ambrosio Chiara C Aprea Noemi N Guerra Gaetano G

ACS omega 20171114 11

A metal-free procedure for oxidation of carbon black (CB), under mild and ecofriendly conditions, is described. The procedure, based on 5/1 w/w H2O2/H2SO4, when applied to high-surface-area CB, leads to oxidation contents (O/C = 0.66) comparable to those obtained for graphite with the more aggressive and metal-based Hummers method (O/C 0.63). Oxidized nanocarbons are able to activate transesterification reactions under solvent-free conditions. Activati ...[more]

PMID: 31457343

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