Unknown

Dataset Information

0

Selective Adsorption of Water, Methanol, and Ethanol by Naphthalene Diimide-Based Coordination Polymers with Constructed Open Cu2+ Metal Sites and Separation of Ethanol/Acetonitrile.


ABSTRACT: The selective separation of ethanol/acetonitrile by porous materials has rarely been observed owing to their similar physicochemical properties. In this work, we report a new coordination network, [Cu2(4-pmntd)2(opd)2](4-pmntd = N,N'-bis(4-pyridymethy)naphthalene diimide, opd = disodium 1,2-benzenedicarboxylate), which exhibits selective separation of ethanol over acetonitrile. The weak coordination bonds formed by unsaturated Cu2+ sites and hydroxyl groups are the key to such performance.

SUBMITTER: Li GB 

PROVIDER: S-EPMC6647964 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC6415121 | biostudies-literature
| S-EPMC9081847 | biostudies-literature
| S-EPMC9297952 | biostudies-literature
| S-EPMC8201227 | biostudies-literature
| S-EPMC8179385 | biostudies-literature
| S-EPMC11372146 | biostudies-literature
| S-EPMC5665789 | biostudies-literature
| S-EPMC5584907 | biostudies-literature
| S-EPMC3558810 | biostudies-literature
| S-EPMC10171628 | biostudies-literature