Production of Nanocellulose Using Hydrated Deep Eutectic Solvent Combined with Ultrasonic Treatment.

ABSTRACT: Pretreatment approaches are highly desirable to improve the commercial viability of nanocellulose production. In this study, we propose a new approach to mass produce nanocellulose using a hydrated choline chloride/oxalic acid dihydrate deep eutectic solvent (DES) combined with an ultrasonic process. The hydrogen bond acidity, polarizability, and solvation effect reflected by the Kamlet-Taft solvatochromic parameters did not decrease even after the addition of large amounts of water. Instead, the water facilitated the ionization of H⁺ and delocalization of Cl^- ions, forming new Cl-H₂O ionic hydrogen and oxalate-H₂O hydrogen bonds, which are critical for improving the solvent characteristics. One pass of kraft pulp through the hydrated DESs (80 °C, 1 h) was sufficient to dissociate the kraft pulp into cellulose nanofibers or cellulose nanocrystals using an 800 W ultrasonic treatment. The present study represents an alternative route for the kraft pulp pretreatment and the large-scale production of nanocellulose.

SUBMITTER: Ma Y 

PROVIDER: S-EPMC6648160 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature