Ontology highlight
ABSTRACT:
SUBMITTER: Marinova M
PROVIDER: S-EPMC6648439 | biostudies-literature | 2019 Feb
REPOSITORIES: biostudies-literature
Marinova Maya M Torres-Werlé Maria M Taupier Grégory G Maisse-François Aline A Achard Thierry T Boeglin Alex A Dorkenoo Kokou Dodzi Honorat KDH Bellemin-Laponnaz Stéphane S
ACS omega 20190205 2
We report an extensive study on the coordination behavior of chiral ditopic bridging ligands, which lead to metallosupramolecular polymers in the presence of Zn(II) and Cu(II) in solution. With the help of UV-vis and circular dichroism spectroscopies, we show that the metallopolymer sequence can be controlled by chirality and by the choice of the metal ion. Although the formation of a block metallopolymer proceeds through the assembly of homoleptic complexes, an alternate metallopolymer may be o ...[more]