Dataset Information

Nitrogen-Doped Alkylamine-Intercalated Layered Titanates for Photocatalytic Dye Degradation.

ABSTRACT: A layered titanate, K₂Ti₄O₉, is intercalated with various n-alkylamines through ion-exchange reaction in aqueous medium. On heating, the intercalated amine is partially deintercalated, yielding nitrogen-doped amine-intercalated titanates. The modified titanates are studied as catalysts in methylene blue degradation under UV irradiation. Heat-treated long-chain amine titanates exhibit better photocatalytic activity in comparison to short chain amine titanates. The improved catalytic activity could be attributed to two factors: (i) increased surface access as the titanate layers are well separated, pillared by the alkylamine chains and (ii) nitrogen doping.

SUBMITTER: A AJ

PROVIDER: S-EPMC6648551 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature

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Nitrogen-Doped Alkylamine-Intercalated Layered Titanates for Photocatalytic Dye Degradation.

A Anto Jeffrey AJ Nethravathi C C Rajamathi Michael M

ACS omega 20190117 1

A layered titanate, K2Ti4O9, is intercalated with various n-alkylamines through ion-exchange reaction in aqueous medium. On heating, the intercalated amine is partially deintercalated, yielding nitrogen-doped amine-intercalated titanates. The modified titanates are studied as catalysts in methylene blue degradation under UV irradiation. Heat-treated long-chain amine titanates exhibit better photocatalytic activity in comparison to short chain amine titanat ...[more]

PMID: 31459418

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Project description:Heterogeneous photocatalysis has been considered one of the most effective and efficient techniques to remove organic contaminants from wastewater. The present work was designed to examine the photocatalytic performance of metal (Cu and Ni) doped ZnO nanocomposites in methyl orange (MO) dye degradation under UV light illumination. The wurtzite hexagonal structure was observed for both undoped/doped ZnO and a crystalline size ranging between 8.84 ± 0.71 to 12.91 ± 0.84 nm by X-ray diffraction (XRD) analysis. The scanning electron microscope (SEM) and energy dispersive X-ray (EDX) revealed the irregular spherical shape with particle diameter (34.43 ± 6.03 to 26.43 ± 4.14 nm) and ensured the purity of the individual elemental composition respectively. The chemical bonds (O-H group) and binding energy (1021.8 eV) were identified by Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) results respectively. The bandgap energy was decreased from 3.44 to 3.16 eV when Ni dopant was added to the ZnO lattice. The comparative photocatalytic activity was observed in undoped and doped nanocomposites and found to be 76.31%, 81.95%, 89.30%, and 83.39% for ZnO, Cu/ZnO, Ni/ZnO, and Cu/Ni/ZnO photocatalysts, respectively, for a particular dose (0.210 g) and dye concentration (10 mg L-1) after 180 min illumination of UV light. The photocatalytic performance was increased up to 94.40% with the increase of pH (12.0) whereas reduced (35.12%) with an increase in initial dye concentration (40 mg L-1) using Ni/ZnO nanocomposite. The Ni/ZnO nanocomposite showed excellent reusability and was found 81% after four consecutive cycles. The best-fitted reaction kinetics was followed by pseudo-first-order and found reaction rate constant (0.0117 min-1) using Ni/ZnO nanocomposite. The enhanced photodegradation efficiency was observed due to decreases in bandgap energy and the crystalline size of the photocatalyst. Therefore, Ni/ZnO nanocomposite could be used as an emerging photocatalyst to degrade bio-persistent organic dye compounds from textile wastewater.

Dataset Information

Nitrogen-Doped Alkylamine-Intercalated Layered Titanates for Photocatalytic Dye Degradation.

Publications

Nitrogen-Doped Alkylamine-Intercalated Layered Titanates for Photocatalytic Dye Degradation.

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