Ontology highlight
ABSTRACT:
SUBMITTER: Peters MK
PROVIDER: S-EPMC6658935 | biostudies-literature | 2019 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20190531 Pt 6
The asymmetric unit of the title compound, [Ni(C<sub>52</sub>H<sub>34</sub>Cl<sub>4</sub>N<sub>4</sub>O<sub>4</sub>)]·CH<sub>2</sub>Cl<sub>2</sub>, consists of two discrete complexes, which show significant differences in the conformation of the side chain. Each Ni<sup>II</sup> cation is coordinated by four nitro-gen atoms of a porphyrin mol-ecule within a square-planar coordination environment. Weak intra-molecular C-H⋯Cl and C-H⋯O inter-actions stabilize the mol-ecular conformation. In the cry ...[more]