Ontology highlight
ABSTRACT:
SUBMITTER: Chen LA
PROVIDER: S-EPMC6663602 | biostudies-literature | 2019 Aug
REPOSITORIES: biostudies-literature
Chen Liang-An LA Lear Alan R AR Gao Pin P Brown M Kevin MK
Angewandte Chemie (International ed. in English) 20190628 32
A method for the construction of boron-substituted quaternary carbons or diarylquaternary carbons by arylboration of highly substituted alkenylarenes is presented. A wide range of alkenes and arylbromides can participate in this reaction thus allowing for a diverse assortment of products to be prepared. In addition, a solvent dependent regiodivergent arylboration of 1,2-disubstituted alkenylarenes is presented, thus greatly increasing the scope of products that can be accessed. ...[more]