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ABSTRACT:
SUBMITTER: Fanfrlik J
PROVIDER: S-EPMC6680755 | biostudies-literature | 2019 Jul
REPOSITORIES: biostudies-literature
Fanfrlík Jindřich J Hnyk Drahomír D Hobza Pavel P
Molecules (Basel, Switzerland) 20190723 14
Chalcogen atoms are a class of substituents capable of generating inner and outer derivatives of boron clusters. It is well known that chalcogenated boron clusters can form strong σ-hole interactions when a chalcogen atom is a part of an icosahedron. This paper studies σ-hole interactions of dicarbaboranes with two exopolyhedral chalcogen atoms bonded to carbon vertices. Specifically, a computational investigation has been carried out on the co-crystal of (1,2-C<sub>2</sub>B<sub>10</sub>H<sub>10 ...[more]