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Stabilization of Polymer Nanocomposites in High-Temperature and High-Salinity Brines.

ABSTRACT: Stabilization of polymer nanocomposites in aqueous environment with high salinity has been a constant challenge for their applications. This work aimed to improve the stability of graphene oxide (GO) polyacrylamide nanocomposites at high-temperature and high-ionic-strength brines. GO was synthesized via a modified Hummers' method and the copolymer of acrylamide (COPAM) was obtained via free-radical polymerization. The covalent functionalization of COPAM with the partially reduced GO (rGO) was successfully achieved. 1,3-Propane sultone was used to further functionalize the obtained rGO-COPAM composites to accomplish the zwitterionic character on the rGO-COPAM surface to get a material with excellent temperature stability and dispersibility in the presence of high ionic strength brines. The synthesized materials were characterized by 1H NMR, gel permeation chromatography, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy analysis, and so forth. The thermal stability of the dispersion at 80 °C for 120 days was observed by visual inspection and spectroscopic analysis. The results showed that the zwitterionic polymer produced excellent brine stability with GO nanosheets and suggested promising applications of zwitterionic polyacrylamide-GO systems especially for enhanced oil recovery.

SUBMITTER: Haruna MA

PROVIDER: S-EPMC6682011 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Stabilization of Polymer Nanocomposites in High-Temperature and High-Salinity Brines.

Haruna Maje Alhaji MA Wen Dongsheng D

ACS omega 20190705 7

Stabilization of polymer nanocomposites in aqueous environment with high salinity has been a constant challenge for their applications. This work aimed to improve the stability of graphene oxide (GO) polyacrylamide nanocomposites at high-temperature and high-ionic-strength brines. GO was synthesized via a modified Hummers' method and the copolymer of acrylamide (COPAM) was obtained via free-radical polymerization. The covalent functionalization of COPAM with the partially reduced GO (rGO) was su ...[more]

PMID: 31460270

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Project description:There is an urgent need for sustainable protein supply routes with low environmental footprint. Recently, the use of hydrogen oxidizing bacteria (HOB) as a platform for high quality microbial protein (MP) production has regained interest. This study aims to investigate the added value of using conditions such as salt and temperature to steer HOB communities to lower diversities, while maintaining a high protein content and a high quality amino acid profile. Pressure drop and hydrogen consumption were measured for 56 days to evaluate autotrophy of a total of six communities in serum flasks. Of the six communities, four were enriched under saline (0.0, 0.25, 0.5 and 1.0 mol NaCl l-1) and two under thermophilic conditions (65°C). Five communities enriched for HOB were subsequently cultivated in continuously stirred reactors under the same conditions to evaluate their potential as microbial protein producers. The protein percentages ranged from 41 to 80%. The highest protein content was obtained for the thermophilic enrichments. Amino acid profiles were comparable to protein sources commonly used for feed purposes. Members of the genus Achromobacter were found to dominate the saline enrichments while members of the genus Hydrogenibacillus were found to dominate the thermophilic enrichments. Here we show that enriching for HOB while steering the community toward low diversity and maintaining a high quality protein content can be successfully achieved, both in saline and thermophilic conditions.IMPORTANCE Alternative feed and food supply chains are required to decrease water and land use. HOB offer a promising substitute for traditional agricultural practice to produce microbial protein (MP) from residual materials and renewable energy. To safeguard product stability, the composition of the HOB community should be controlled. Defining strategies to maintain the stability of the communities is therefore key for optimization purposes. In this study, we use salt and temperature as independent conditions to stabilize the composition of the HOB communities. Based on the results presented, we conclude that HOB communities can be steered to have low diversity using the presented conditions while producing a desirable protein content with a valuable amino acid profile.

Dataset Information

Stabilization of Polymer Nanocomposites in High-Temperature and High-Salinity Brines.

Publications

Stabilization of Polymer Nanocomposites in High-Temperature and High-Salinity Brines.

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