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Comparative Study on Enhancing Oil Recovery under High Temperature and High Salinity: Polysaccharides Versus Synthetic Polymer.

ABSTRACT: The synthetic water-soluble polymer, partially hydrolyzed polyacrylamide (HPAM), has been most widely used for enhanced oil recovery (EOR); however, its poor thermal stability and weak salt tolerance impede further application in high-temperature and high-salinity oil reservoirs. To address such deficiencies, three polysaccharides, xanthan gum, diutan gum, and scleroglucan, were examined in comparison with HPAM on rheological behaviors, shearing resistance, long-term thermal stability, and core flooding test. It was found that all of these three polysaccharides were less sensitive to salinity and shearing time, while HPAM showed a monotonous decrease in viscosity with increasing monovalent cations and shearing history. After 90 days of aging at 85 °C and 10.1 × 104 mg·L-1 of total dissolved solids with 1.0 × 103 mg·L-1 of Ca2+, the viscosity of diutan gum and scleroglucan solutions nearly remained unchanged; on the contrary, the viscosity of xanthan gum and HPAM solutions drops massively. Core flooding tests at 85 °C with the same initial viscosity demonstrated that all polymers showed good transportation in porous media, and 16, 13, and 11% of oil recovery were obtained by diutan gum, scleroglucan, and xanthan gum, respectively, while only 10% was obtained from HPAM. These comparative results may underpin the potential of diutan gum and scleroglucan to be used in the EOR process in HTHS oil reservoirs.

SUBMITTER: Liang K

PROVIDER: S-EPMC6648808 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Comparative Study on Enhancing Oil Recovery under High Temperature and High Salinity: Polysaccharides Versus Synthetic Polymer.

Liang Ke K Han Peihui P Chen Quansheng Q Su Xin X Feng Yujun Y

ACS omega 20190619 6

The synthetic water-soluble polymer, partially hydrolyzed polyacrylamide (HPAM), has been most widely used for enhanced oil recovery (EOR); however, its poor thermal stability and weak salt tolerance impede further application in high-temperature and high-salinity oil reservoirs. To address such deficiencies, three polysaccharides, xanthan gum, diutan gum, and scleroglucan, were examined in comparison with HPAM on rheological behaviors, shearing resistance, long-term thermal stability, and core ...[more]

PMID: 31460160

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Project description:Low salinity waterflooding (low salinity-EOR) has attracted great interest from many giant oil producers and is currently under trial in some of the oil fields of the United States, Middle Eastern countries, and North Sea reservoirs. Most of the reported studies on this process were carried out for medium to relatively heavy oil with significant polar contents. In this work, we have investigated low salinity waterflooding performance for light paraffinic crude oil with a low acid number. This study has been performed using crude oil from an Indian offshore oilfield and Indian offshore seawater. Oil recovery efficiencies of seawater and its diluted versions (low salinity seawater) were evaluated through core-flooding experiments performed on a silica sand pack containing small amounts (2 wt %) of bentonite clay saturated with crude oil. Interfacial tension and wettability studies were performed to understand the associated low salinity effects on the crude oil/brine/rock properties. Effluent brine produced during the flooding experiments was also analyzed to obtain a clearer insight into the low salinity-enhanced oil recovery (EOR) mechanism. The results showed that injection of low salinity seawater can significantly increase the waterflood recovery in comparison with high salinity seawater injection. Interfacial tension and contact angle studies revealed that there is an optimum dilution level at which the interfacial tension and wettability are the most favorable for enhanced oil recovery even in the case of light paraffinic crude. These results are in line with the results obtained from the core-flooding experiments. The possible reason behind recovery improvement based on the interfacial tension and wettability studies in conjugation with the effluent brine analysis has been discussed in detail. In this study, we have observed that the enhanced oil recovery efficiency could be achieved by applying low salinity seawater flooding even in the case of light paraffinic oil with a low acid number.

Dataset Information

Comparative Study on Enhancing Oil Recovery under High Temperature and High Salinity: Polysaccharides Versus Synthetic Polymer.

Publications

Comparative Study on Enhancing Oil Recovery under High Temperature and High Salinity: Polysaccharides Versus Synthetic Polymer.

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