Dataset Information

Reduced Graphene Oxide-Conjugated Urchin-Like NiCo2O4 Nanostructures for Individual Detection of o-Nitro and p-Amino Phenol.

ABSTRACT: This work introduced a facile synthesis method of reduced graphene oxide-conjugated urchin-like NiCo2O4 nanostructures via a simple, cost-effective, and environmental-friendly one-pot hydrothermal method. The as-prepared rGO-NiCo2O4 nanocomposites were used to fabricate 3-aminopropyltriethoxysilane-modified glassy carbon electrode (GCE/APTES/rGO-NiCo2O4) for ultrasensitive electrochemical detection of o-nitro (o-NP) and p-amino (p-AP) phenols. The structure and morphology of the nanocomposite were characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. Electrochemical experiments revealed that the nanocomposite exhibited remarkable electrochemical performances. A linear relationship is observed with the differential pulse voltammetry experiment between the peak currents and the concentrations in the ranges of 5.0 × 10-9 to 5.0 × 10-7 M (R 2 = 0.996) and 1.0 × 10-6 to 2.5 × 10-5 M (R 2 = 0.992) for o-NP and of 1.0 × 10-8 to 5.0 × 10-7 M (R 2 = 0.996) and 1.0 × 10-6 to 1.0 × 10-4 M (R 2 = 0.987) for p-AP. The calculated detection limits (S/N = 3) are 5.0 × 10-9 M and 1.0 ×10-8 M for o-NP and p-AP, respectively. Furthermore, a very high recovery percentage is obtained with the proposed sensor after successful application in the determination of target analytes in tap water samples.

SUBMITTER: Khan MZH

PROVIDER: S-EPMC6682125 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Reduced Graphene Oxide-Conjugated Urchin-Like NiCo2O4 Nanostructures for Individual Detection of o-Nitro and p-Amino Phenol.

Khan Md Zaved H MZH Zhu Jinhua J Liu Xiuhua X

ACS omega 20190701 7

This work introduced a facile synthesis method of reduced graphene oxide-conjugated urchin-like NiCo2O4 nanostructures via a simple, cost-effective, and environmental-friendly one-pot hydrothermal method. The as-prepared rGO-NiCo2O4 nanocomposites were used to fabricate 3-aminopropyltriethoxysilane-modified glassy carbon electrode (GCE/APTES/rGO-NiCo2O4) for ultrasensitive electrochemical detection of o-nitro (o-NP) ...[more]

PMID: 31460248

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Project description:Transition metal sulfide semiconductors have achieved significant attention in the field of photocatalysis and degradation of pollutants. MoS2 with a two dimensional (2D) layered structure, a narrow bandgap and the ability of getting excited while being exposed to visible light, has demonstrated great potential in visible-light-driven photocatalysts. However, it possesses fast-paced recombination of charges. In this study, the coupled MoS2 nanosheets were synthesized with ZnO nanorods to develop the heterojunctions photocatalyst in order to obtain superior photoactivity. The charge transfer in this composite is not adequate to achieve desirable activity. Therefore, heterojunction was modified by reduced graphene oxide (RGO) nanosheets and carbon nanotubes (CNTs) to develop the RGO/ZnO/MoS2 and CNTs/ZnO/MoS2 ternary nanocomposites. The structure, morphology, composition, optical and photocatalytic properties of the as-fabricated samples were characterized through X-ray diffraction (XRD), Fourier Transform Infrared (FTIR), Field Emission Scanning Electron Microscopy (FESEM), Transmission Electron Microscopy (TEM), Energy-Dispersive X-ray (EDX), elemental mapping, Photoluminescence (PL), Ultraviolet-Visible spectroscopy (UV-VIS), and Brunauer-Emmett-Teller (BET) techniques. The photo-catalytic performance of all samples was evaluated through photodegradation of aniline in aqueous solution. The combination of RGO or CNTs into the ZnO/MoS2 greatly promoted the catalytic activity. However, the resulting RGO/ZnO/MoS2 ternary nanocomposites showed appreciably increased catalytic performance, faster than that of CNTs/ZnO/MoS2. Charge carrier transfer studies, the BET surface area analysis, and the optical studies confirmed this superiority. The role of operational variables namely, solution pH, catalyst dosage amount, and initial concentration of aniline was then investigated for obtaining maximum degradation. Complete degradation was observed, in the case of pH = 4, catalyst dosage of 0.7 g/L and aniline concentration of 80 ppm, and light intensity of 100 W. According to the results of trapping experiments, hydroxyl radical was found to be the main active species in the photocatalytic reaction. Meanwhile, a plausible mechanism was proposed for describing the degradation of aniline upon ternary composite. Moreover, the catalyst showed excellent reusability and stability after five consecutive cycles due to the synergistic effect between its components. Total-Organic-Carbon concentration (TOC) results suggested that complete mineralization of aniline occurred after 210 min of irradiation. Finally, a real petrochemical wastewater sample was evaluated for testing the catalytic ability of the as-fabricated composites in real case studies and it was observed that the process successfully quenched 100% and 93% of Chemical Oxygen Demand (COD) and TOC in the wastewater, respectively.

Dataset Information

Reduced Graphene Oxide-Conjugated Urchin-Like NiCo2O4 Nanostructures for Individual Detection of o-Nitro and p-Amino Phenol.

Publications

Reduced Graphene Oxide-Conjugated Urchin-Like NiCo<sub>2</sub>O<sub>4</sub> Nanostructures for Individual Detection of <i>o</i>-Nitro and <i>p</i>-Amino Phenol.

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