Ontology highlight
ABSTRACT:
SUBMITTER: Wang D
PROVIDER: S-EPMC6684548 | biostudies-literature | 2019 Aug
REPOSITORIES: biostudies-literature
Nature communications 20190806 1
Biarylphosphines have been widely applied as ligands in various synthetic methods, especially in transition-metal-catalysed carbon-carbon and carbon-heteroatom bond cross-coupling reactions. Based on the outstanding properties of the parent scaffolds, a general method for in situ modification of the commercial tertiary phosphine ligands to access a series of ligands is in high demand. Here we show that a rhodium-catalysed system is introduced for the hydroarylation of alkenes and alkynes with te ...[more]