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Spontaneous Formation of a Cross-Linked Supramolecular Polymer Both in the Solid State and in Solution, Driven by Platinum(II) Metallacycle-Based Host-Guest Interactions.

ABSTRACT: The recent progress in platinum(II) coordination-driven supramolecular polymers has had a substantial effect on the design of functional soft materials. However, the prospect of realizing polymerization induced by platinum(II) metallacycle-based host-guest interactions has received little attention until recently. Here we report the realization of supramolecular polymerization driven by platinum(II) metallacycle-based host-guest interactions both in the solid state and in solution. On the basis of the disclosed polymerization mechanism, we present a new strategy for the preparation of platinum(II) metallacycle-based supramolecular polymers.

SUBMITTER: Shi B

PROVIDER: S-EPMC6690365 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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Spontaneous Formation of a Cross-Linked Supramolecular Polymer Both in the Solid State and in Solution, Driven by Platinum(II) Metallacycle-Based Host-Guest Interactions.

Shi Bingbing B Liu Yuezhou Y Zhu Huangtianzhi H Vanderlinden Ryan T RT Shangguan Liqing L Ni Ruidong R Acharyya Koushik K Tang Jian-Hong JH Zhou Zhixuan Z Li Xiaopeng X Huang Feihe F Stang Peter J PJ

Journal of the American Chemical Society 20190412 16

The recent progress in platinum(II) coordination-driven supramolecular polymers has had a substantial effect on the design of functional soft materials. However, the prospect of realizing polymerization induced by platinum(II) metallacycle-based host-guest interactions has received little attention until recently. Here we report the realization of supramolecular polymerization driven by platinum(II) metallacycle-based host-guest interactions both in the solid state and in solution. On the basis ...[more]

PMID: 30966741

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