Upcycling of polyurethane waste by mechanochemistry: synthesis of N-doped porous carbon materials for supercapacitor applications.

ABSTRACT: We developed an upcycling process of polyurethane obtaining porous nitrogen-doped carbon materials that were applied in supercapacitor electrodes. In detail, a mechanochemical solvent-free one-pot synthesis is used and combined with a thermal treatment. Polyurethane is an ideal precursor already containing nitrogen in its backbone, yielding nitrogen-doped porous carbon materials with N content values of 1-8 wt %, high specific surface area values of up to 2150 m2·g-1 (at a N content of 1.6 wt %) and large pore volume values of up to 0.9 cm3·g-1. The materials were tested as electrodes for supercapacitors in aqueous 1 M Li2SO4 electrolyte (100 F·g-1), organic 1 M TEA-BF4 (ACN, 83 F·g-1) and EMIM-BF4 (70 F·g-1).

SUBMITTER: Schneidermann C 

PROVIDER: S-EPMC6693373 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature