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Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources.

ABSTRACT: An eco-friendly method for the synthesis of ?-alkoxy sulfones via electrochemical alkoxysulfonylation reaction of styrenes with sodium sulfinates as sulfonyl sources has been established. The reaction is conducted in an undivided cell at room temperature and tolerates a wide scope of styrenes, sodium sulfinates, and alcohols. The reaction does not need any chemical oxidants and transition-metal catalysts, which provides a new and green access to ?-alkoxy sulfones.

SUBMITTER: Mei H

PROVIDER: S-EPMC6733175 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources.

Mei Haibo H Liu Jiang J Guo Yunjie Y Han Jianlin J

ACS omega 20190820 10

An eco-friendly method for the synthesis of β-alkoxy sulfones via electrochemical alkoxysulfonylation reaction of styrenes with sodium sulfinates as sulfonyl sources has been established. The reaction is conducted in an undivided cell at room temperature and tolerates a wide scope of styrenes, sodium sulfinates, and alcohols. The reaction does not need any chemical oxidants and transition-metal catalysts, which provides a new and green access to β-alkoxy sulfones. ...[more]

PMID: 31508561

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