Dataset Information

Variation of Mechanical Characteristics of Polyurethane Foam: Effect of Test Method.

ABSTRACT: Polyurethane foam (PUF), a representative insulation material, not only prevents heat conduction but can also support a load. Particular interest in rigid PUF proliferated over the past several years in fields where extreme environments are applied. A closed-cell structure which forms the interior of rigid PUF serves to maximize the utilization of these polymeric foams. Rigid PUF is more sensitive to external conditions such as temperature or restraint than other structural materials such as steel. Depending on the market trends in which utilization of a cryogenic environment is expanding, the tendency of material behavior resulting from the binding effect also needs to be investigated. However, most conventional compression test method standards applicable to rigid PUF do not adequately reflect the restraints. Therefore, this study proposes a method for evaluating the mechanical performance of materials in a more reliable manner than that of conventional tests. Experimental observation and analysis validated this compression evaluation method in which constraints are considered. Consequently, the compressive strength of rigid PUF compared to the results of the conventional test showed a difference of up to 0.47 MPa (approximately 23%) at cryogenic temperatures. This result suggests that there are important factors to consider when assessing performance from a material perspective in an environment where rigid PUF insulation is utilized. It is believed that the test methods newly proposed in this study will provide an experimental framework that can be applied to the evaluation criteria of material properties and reflected in structural design.

SUBMITTER: Park KB

PROVIDER: S-EPMC6747564 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

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Variation of Mechanical Characteristics of Polyurethane Foam: Effect of Test Method.

Park Ki-Beom KB Kim Hee-Tae HT Her Nam-Yong NY Lee Jae-Myung JM

Materials (Basel, Switzerland) 20190822 17

Polyurethane foam (PUF), a representative insulation material, not only prevents heat conduction but can also support a load. Particular interest in rigid PUF proliferated over the past several years in fields where extreme environments are applied. A closed-cell structure which forms the interior of rigid PUF serves to maximize the utilization of these polymeric foams. Rigid PUF is more sensitive to external conditions such as temperature or restraint than other structural materials such as ste ...[more]

PMID: 31443352

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Project description:With the phase-out of PentaBDE in 2004, alternative flame retardants are being used in polyurethane foam to meet flammability standards. However, insufficient information is available on the identity of the flame retardants currently in use. Baby products containing polyurethane foam must meet California state furniture flammability standards, which likely affects the use of flame retardants in baby products throughout the U.S. However, it is unclear which products contain flame retardants and at what concentrations. In this study we surveyed baby products containing polyurethane foam to investigate how often flame retardants were used in these products. Information on when the products were purchased and whether they contained a label indicating that the product meets requirements for a California flammability standard were recorded. When possible, we identified the flame retardants being used and their concentrations in the foam. Foam samples collected from 101 commonly used baby products were analyzed. Eighty samples contained an identifiable flame retardant additive, and all but one of these was either chlorinated or brominated. The most common flame retardant detected was tris(1,3-dichloroisopropyl) phosphate (TDCPP; detection frequency 36%), followed by components typically found in the Firemaster550 commercial mixture (detection frequency 17%). Five samples contained PBDE congeners commonly associated with PentaBDE, suggesting products with PentaBDE are still in-use. Two chlorinated organophosphate flame retardants (OPFRs) not previously documented in the environment were also identified, one of which is commercially sold as V6 (detection frequency 15%) and contains tris(2-chloroethyl) phosphate (TCEP) as an impurity. As an addition to this study, we used a portable X-ray fluorescence (XRF) analyzer to estimate the bromine and chlorine content of the foam and investigate whether XRF is a useful method for predicting the presence of halogenated flame retardant additives in these products. A significant correlation was observed for bromine; however, there was no significant relationship observed for chlorine. To the authors knowledge, this is the first study to report on flame retardants in baby products. In addition, we have identified two chlorinated OPFRs not previously documented in the environment or in consumer products. Based on exposure estimates conducted by the Consumer Product Safety Commission (CPSC), we predict that infants may receive greater exposure to TDCPP from these products compared to the average child or adult from upholstered furniture, all of which are higher than acceptable daily intake levels of TDCPP set by the CPSC. Future studies are therefore warranted to specifically measure infants exposure to these flame retardants from intimate contact with these products and to determine if there are any associated health concerns.

Dataset Information

Variation of Mechanical Characteristics of Polyurethane Foam: Effect of Test Method.

Publications

Variation of Mechanical Characteristics of Polyurethane Foam: Effect of Test Method.

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