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A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework.


ABSTRACT: A novel one-dimensional covalent organic framework (COF-K) was firstly designed and synthesized through a Schiff-based reaction from a porphyrin building block and a nonlinear right-angle building block. The COF-K exhibited high BET surface area and narrow pore size of 1.25 nm and gave a CO2 adsorption capacity of 89 mg g-1 at 273K and 1bar.

SUBMITTER: Zhang M 

PROVIDER: S-EPMC6767199 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework.

Zhang Miao M   Zheng Ruijin R   Ma Ying Y   Chen Ruiping R   Sun Xun X   Sun Xuan X  

Molecules (Basel, Switzerland) 20190916 18


A novel one-dimensional covalent organic framework (COF-K) was firstly designed and synthesized through a Schiff-based reaction from a porphyrin building block and a nonlinear right-angle building block. The COF-K exhibited high BET surface area and narrow pore size of 1.25 nm and gave a CO<sub>2</sub> adsorption capacity of 89 mg g<sup>-1</sup> at 273K and 1bar. ...[more]

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