Ontology highlight
ABSTRACT:
SUBMITTER: Xu HS
PROVIDER: S-EPMC7080745 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Nature communications 20200318 1
Although polymers have been studied for well over a century, there are few examples of covalently linked polymer crystals synthesised directly from solution. One-dimensional (1D) covalent polymers that are packed into a framework structure can be viewed as a 1D covalent organic framework (COF), but making a single crystal of this has been elusive. Herein, by combining labile metal coordination and dynamic covalent chemistry, we discover a strategy to synthesise single-crystal metallo-COFs under ...[more]