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Pulsed laser synthesis of highly active Ag-Rh and Ag-Pt antenna-reactor-type plasmonic catalysts.


ABSTRACT: Ag, Pt, and Rh monometallic colloids were produced via laser ablation. Separate Ag-Rh and Ag-Pt heterostructures were formed by mixing and resulted in groupings of Rh/Pt nanoparticles adsorbing to the concavities of the larger Ag nanostructures. The 400 nm Ag plasmonic absorption peak was slightly blue-shifted for Ag-Pt and red-shifted for Ag-Rh heterostructures. Catalytic activity for the reduction of 4-nitrophenol increased significantly for Ag-Pt and Ag-Rh compared to the monometallic constituents, and persisted at lower loading ratios and consecutive reduction cycles. The enhancement is attributed to the Rh and Pt nanoparticles forming antenna-reactor-type plasmonic catalysts with the Ag nanostructures.

SUBMITTER: Kane KA 

PROVIDER: S-EPMC6774074 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature

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Pulsed laser synthesis of highly active Ag-Rh and Ag-Pt antenna-reactor-type plasmonic catalysts.

Kane Kenneth A KA   Bertino Massimo F MF  

Beilstein journal of nanotechnology 20190926


Ag, Pt, and Rh monometallic colloids were produced via laser ablation. Separate Ag-Rh and Ag-Pt heterostructures were formed by mixing and resulted in groupings of Rh/Pt nanoparticles adsorbing to the concavities of the larger Ag nanostructures. The 400 nm Ag plasmonic absorption peak was slightly blue-shifted for Ag-Pt and red-shifted for Ag-Rh heterostructures. Catalytic activity for the reduction of 4-nitrophenol increased significantly for Ag-Pt and Ag-Rh compared to the monometallic constit  ...[more]

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