Ni_0.5Cu_0.5Co₂O₄ Nanocomposites, Morphology, Controlled Synthesis, and Catalytic Performance in the Hydrolysis of Ammonia Borane for Hydrogen Production.

ABSTRACT: The catalytic hydrolysis of ammonia borane (AB) is a promising route to produce hydrogen for mobile hydrogen?oxygen fuel cells. In this study, we have successfully synthesized a variety of Ni_0.5Cu_0.5Co₂O₄ nanocomposites with different morphology, including nanoplatelets, nanoparticles, and urchin-like microspheres. The catalytic performance of those Ni_0.5Cu_0.5Co₂O₄ composites in AB hydrolysis is investigated. The Ni_0.5Cu_0.5Co₂O₄ nanoplatelets show the best catalytic performance despite having the smallest specific surface area, with a turnover frequency (TOF) of 80.2 mol_hydrogen·min^-1·mol^-1_cat. The results reveal that, in contrast to the Ni_0.5Cu_0.5Co₂O₄ nanoparticles and microspheres, the Ni_0.5Cu_0.5Co₂O₄ nanoplatelets are more readily reduced, leading to the fast formation of active species for AB hydrolysis. These findings provide some insight into the design of high-performance oxide-based catalysts for AB hydrolysis. Considering their low cost and high catalytic activity, Ni_0.5Cu_0.5Co₂O₄ nanoplatelets are a strong candidate catalyst for the production of hydrogen through AB hydrolysis in practical applications.

SUBMITTER: Feng Y 

PROVIDER: S-EPMC6781025 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature