BN- and BO-Doped Inorganic-Organic Hybrid Polymers with Sulfoximine Core Units.
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ABSTRACT: While polysulfones constitute a class of well-established, highly valuable applied materials, knowledge about polymers based on the related sulfoximine group is very limited. We have employed functionalized diaryl sulfoximines and a p-phenylene bisborane as building blocks for unprecedented BN- and BO-doped alternating inorganic-organic hybrid copolymers. While the former were accessed by a facile silicon/boron exchange protocol, the synthesis of polymers with main-chain B-O linkages was achieved by salt elimination.
SUBMITTER: Brosge F
PROVIDER: S-EPMC6790941 | biostudies-literature |
REPOSITORIES: biostudies-literature
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