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Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs.

ABSTRACT: Hexacarboxylates are promising linkers for MOFs such as NU-109 or NU-110, which possess large values for surfaces and pore volumina. Starting from 2,4,6-tris(bromoaryl)-1,3,5-triazines, palladium-catalyzed cross coupling reactions (Suzuki-Miyaura, Sonogashira-Hagihara) form elongated hexacarboxylate linkers. Eight new 2,4,6-tris(biphenyl) and 2,4,6-tris(phenylethynylphenyl) 1,3,5-triazines have been prepared in quantities ranging from 40 mg to 1.1 g. In five cases, one of the arms of the linker carries an additional functionality (NO2 or OMe).

SUBMITTER: Klinkebiel A

PROVIDER: S-EPMC6804050 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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Substituted 1,3,5-Triazine Hexacarboxylates as Potential Linkers for MOFs.

Klinkebiel Arne A Beyer Ole O Lüning Ulrich U

Molecules (Basel, Switzerland) 20190925 19

Hexacarboxylates are promising linkers for MOFs such as NU-109 or NU-110, which possess large values for surfaces and pore volumina. Starting from 2,4,6-tris(bromoaryl)-1,3,5-triazines, palladium-catalyzed cross coupling reactions (Suzuki-Miyaura, Sonogashira-Hagihara) form elongated hexacarboxylate linkers. Eight new 2,4,6-tris(biphenyl) and 2,4,6-tris(phenylethynylphenyl) 1,3,5-triazines have been prepared in quantities ranging from 40 mg to 1.1 g. In five cases, one of the arms of the linker ...[more]

PMID: 31557929

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