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Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II).


ABSTRACT: In the title complex, [MnCl(2)(C(18)H(12)N(6))], the Mn(II) ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the mol-ecules are stacked in columns along the c axis and display inter-molecular ?-? inter-actions between the six-membered rings, the shortest centroid-centroid distance being 3.553?(3)Å. Inter-molecular C-H?Cl contacts are also noted.

SUBMITTER: Ha K 

PROVIDER: S-EPMC2983677 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II).

Ha Kwang K  

Acta crystallographica. Section E, Structure reports online 20100206 Pt 3


In the title complex, [MnCl(2)(C(18)H(12)N(6))], the Mn(II) ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the mol-ecules are stacked in columns along the c axis and display inter-molecular π-π inter-actions between the six-membered rings, the shortest centroid-centroid distance being 3.553 (3)Å. Inter-molecular C-H⋯Cl contacts are also noted. ...[more]

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