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One-dimensional ladder gallium coordination polymer.

ABSTRACT: A one-dimensional ladder-type coordination polymer, poly[[(?2-hydroxido)(?2-1H-pyrazole-3,5-di-carboxyl-ato)gallium(III)] monohydrate], [Ga(C5H2N2O4)(OH)(H2O)] n or [Ga(HPDC)(OH)(H2O)] n , I, isotypic with a V3+ coordination polymer previously reported by Chen et al. [J. Coord. Chem. (2008). 61, 3556-3567] was prepared from Ga3+ and pyrazole-3,5-di-carb-oxy-lic acid monohydrate (H3PDC·H2O). Compound I was isolated using three distinct experimental methods: hydro-thermal (HT), microwave-assisted (MWAS) and one-pot (OP) and the crystallite size should be fine-tuned according to the method employed. The coordination polymeric structure is based on a dimeric Ga3+ moiety comprising two ?2-bridging hydroxide groups, which are inter-connected by HPDC2- anionic organic linkers. The close packing of individual polymers is strongly directed by the supra-molecular inter-actions, namely several O-H?O and N-H?O hydrogen-bonding inter-actions.

SUBMITTER: Simoes AB 

PROVIDER: S-EPMC6829714 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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One-dimensional ladder gallium coordination polymer.

Simões Andrea B AB   Figueira Flávio F   Mendes Ricardo F RF   Barbosa Jéssica S JS   Rocha João J   Paz Filipe A Almeida FAA  

Acta crystallographica. Section E, Crystallographic communications 20191003 Pt 11

A one-dimensional ladder-type coordination polymer, poly[[(μ<sub>2</sub>-hydroxido)(μ<sub>2</sub>-1<i>H</i>-pyrazole-3,5-di-carboxyl-ato)gallium(III)] monohydrate], [Ga(C<sub>5</sub>H<sub>2</sub>N<sub>2</sub>O<sub>4</sub>)(OH)(H<sub>2</sub>O)] <sub><i>n</i></sub> or [Ga(HPDC)(OH)(H<sub>2</sub>O)] <sub><i>n</i></sub> , <b>I</b>, isotypic with a V<sup>3+</sup> coordination polymer previously reported by Chen <i>et al.</i> [<i>J. Coord. Chem.</i> (2008). <b>61</b>, 3556-3567] was prepared from Ga<s  ...[more]

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