Ontology highlight
ABSTRACT:
SUBMITTER: Mehdi MA
PROVIDER: S-EPMC6854560 | biostudies-literature | 2019 Nov
REPOSITORIES: biostudies-literature
Mehdi Mariam A MA Bushnell Eric A C EAC Nikoo Sahar S Gauld James W JW Green James R JR
ACS omega 20191028 20
A series of 7-methylenedehydrobenzo[7]annulen-5-ol hexacarbonyldicobalt complexes were generated by Hosomi-Sakurai reactions of allylsilanes containing <i>o</i>-alkynylarylaldehyde-Co<sub>2</sub>(CO)<sub>6</sub> complexes. One of the cyclization products was converted into its corresponding dihydrobenzo[7]annulen-7-ol hexacarbonyldicobalt complex, an immediate precursor to a benzodehydrotropylium-Co<sub>2</sub>(CO)<sub>6</sub>. The cation was generated in situ and reacted with four nucleophiles, ...[more]