Ontology highlight
ABSTRACT:
SUBMITTER: Hu X
PROVIDER: S-EPMC6884519 | biostudies-literature | 2019 Nov
REPOSITORIES: biostudies-literature
Hu Xia X Zhang Guoting G Nie Lei L Kong Taige T Lei Aiwen A
Nature communications 20191129 1
The dehydrogenative aryl C-H/N-H cross-coupling is a powerful synthetic methodology to install nitrogen functionalities into aromatic compounds. Herein, we report an electrochemical oxidation induced intermolecular cross-coupling between aromatics and sulfonimides with high regioselectivity through N-radical addition pathway under external-oxidant-free and catalyst-free conditions. A wide variety of arenes, heteroarenes, alkenes and sulfonimides are applicable scaffolds in this transformation. I ...[more]