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A Novel Ruthenium(II) Polypyridyl Complex Bearing 1,8-Naphthyridine as a High Selectivity and Sensitivity Fluorescent Chemosensor for Cu2+ and Fe3+ Ions.


ABSTRACT: A novel ruthenium(II) polypyridyl complex bearing 1,8-naphthyridine was successfully designed and synthesized. This complex was fully characterized by EI-HRMS, NMR, and elemental analyses. The recognition properties of the complex for various metal ions were investigated. The results suggested that the complex displayed high selectivity and sensitivity for Cu2+ and Fe3+ ions with good anti-interference in the CH3CN/H2O (1:1, v/v) solution. The fluorescent chemosensor showed obvious fluorescence quenching when the Cu2+ and Fe3+ ions were added. The detection limits of Cu2+ and Fe3+ were 39.9 nmol/L and 6.68 nmol/L, respectively. This study suggested that this Ru(II) polypyridyl complex can be used as a high selectivity and sensitivity fluorescent chemosensor for Cu2+ and Fe3+ ions.

SUBMITTER: He C 

PROVIDER: S-EPMC6891798 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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A Novel Ruthenium(II) Polypyridyl Complex Bearing 1,8-Naphthyridine as a High Selectivity and Sensitivity Fluorescent Chemosensor for Cu<sup>2+</sup> and Fe<sup>3+</sup> Ions.

He Chixian C   Yu Shiwen S   Ma Shuye S   Liu Zining Z   Yao Lifeng L   Cheng Feixiang F   Liu Pinhua P  

Molecules (Basel, Switzerland) 20191107 22


A novel ruthenium(II) polypyridyl complex bearing 1,8-naphthyridine was successfully designed and synthesized. This complex was fully characterized by EI-HRMS, NMR, and elemental analyses. The recognition properties of the complex for various metal ions were investigated. The results suggested that the complex displayed high selectivity and sensitivity for Cu<sup>2+</sup> and Fe<sup>3+</sup> ions with good anti-interference in the CH<sub>3</sub>CN/H<sub>2</sub>O (1:1, <i>v</i>/<i>v</i>) solution  ...[more]

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