Ontology highlight
ABSTRACT:
SUBMITTER: Martinez-Martinez AJ
PROVIDER: S-EPMC6899477 | biostudies-literature | 2019 Nov
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20191011 47
Reversible encapsulation of CH<sub>2</sub> Cl<sub>2</sub> or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy<sub>2</sub> PCH<sub>2</sub> PCy<sub>2</sub> )(NBD)][BAr<sup>F</sup><sub>4</sub> ] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including <sup>129</sup> Xe SSNMR. Non-covalent interactions with the -CF<sub>3</sub> groups, and hydrophobic channels formed, of [BAr<sup>F</sup><sub>4</sub> ]< ...[more]