Dataset Information

Oblique Electrostatic Inkjet-Deposited TiO₂ Electron Transport Layers for Efficient Planar Perovskite Solar Cells.

ABSTRACT: In this study, a new, simple, and novel oblique electrostatic inkjet (OEI) technique is developed to deposit a titanium oxide (TiO₂) compact layer (CL) on fluorine-doped tin oxide (FTO) substrate without the need for a vacuum environment for the first time. The TiO₂ is used as electron transport layers (ETL) in planar perovskite solar cells (PSCs). This bottom-up OEI technique enables the control of the surface morphology and thickness of the TiO₂ CL by simply manipulating the coating time. The OEI-fabricated TiO₂ is characterized tested and the results are compared with that of TiO₂ CLs produced by spin-coating and spray pyrolysis. The OEI-deposited TiO₂ CL exhibits satisfactory surface coverage and smooth morphology, conducive for the ETLs in PSCs. The power-conversion efficiencies of PSCs with OEI-deposited TiO₂ CL as the ETL were as high as 13.19%. Therefore, the present study provides an important advance in the effort to develop simple, low-cost, and easily scaled-up techniques. OEI may be a new candidate for depositing TiO₂ CL ETLs for highly efficient planar PSCs, thus potentially contributing to future mass production.

SUBMITTER: Shahiduzzaman M

PROVIDER: S-EPMC6925098 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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Oblique Electrostatic Inkjet-Deposited TiO2 Electron Transport Layers for Efficient Planar Perovskite Solar Cells.

Shahiduzzaman Md M Sakuma Toshiharu T Kaneko Tetsuya T Tomita Koji K Isomura Masao M Taima Tetsuya T Umezu Shinjiro S Iwamori Satoru S

Scientific reports 20191220 1

In this study, a new, simple, and novel oblique electrostatic inkjet (OEI) technique is developed to deposit a titanium oxide (TiO2) compact layer (CL) on fluorine-doped tin oxide (FTO) substrate without the need for a vacuum environment for the first time. The TiO2 is used as electron transport layers (ETL) in planar perovskite solar cells (PSCs). This bottom-up OEI technique enables the control of the surface morphology and thickness of the TiO2 CL by simply ma ...[more]

PMID: 31862974

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Project description:The exceptional property of plasmonic materials to localize light into sub-wavelength regimes has significant importance in various applications, especially in photovoltaics. In this study, we report the localized surface plasmon-enhanced perovskite solar cell (PSC) performance of plasmonic gold nanoparticles (AuNPs) embedded into a titanium oxide (TiO2) microdot array (MDA), which was deposited using the inkjet printing technique. The X-ray (XRD) analysis of MAPI (methyl ammonium lead iodide) perovskite films deposited on glass substrates with and without MDA revealed no destructive effect of MDA on the perovskite structure. Moreover, a 12% increase in the crystallite size of perovskite with MDA was registered. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HR-TEM) techniques revealed the morphology of the TiO2_MDA and TiO2-AuNPs_MDA. The finite-difference time-domain (FDTD) simulation was employed to evaluate the absorption cross-sections and local field enhancement of AuNPs in the TiO2 and TiO2/MAPI surrounding media. Reflectance UV-Vis spectra of the samples comprising glass/TiO2 ETL/TiO2_MDA (ETL-an electron transport layer) with and without AuNPs in TiO2_MDA were studied, and the band gap (Eg) values of MAPI have been calculated using the Kubelka-Munk equation. The MDA introduction did not influence the band gap value, which remained at ~1.6 eV for all the samples. The photovoltaic performance of the fabricated PSC with and without MDA and the corresponding key parameters of the solar cells have also been studied and discussed in detail. The findings indicated a significant power conversion efficiency improvement of over 47% in the PSCs with the introduction of the TiO2-AuNPs_MDA on the ETL/MAPI interface compared to the reference device. Our study demonstrates the significant enhancement achieved in halide PSC by utilizing AuNPs within a TiO2_MDA. This approach holds great promise for advancing the efficiency and performance of photovoltaic devices.

Dataset Information

Oblique Electrostatic Inkjet-Deposited TiO₂ Electron Transport Layers for Efficient Planar Perovskite Solar Cells.

Publications

Oblique Electrostatic Inkjet-Deposited TiO<sub>2</sub> Electron Transport Layers for Efficient Planar Perovskite Solar Cells.

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