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Inkjet-Printed Electron Transport Layers for Perovskite Solar Cells.

ABSTRACT: Inkjet printing emerged as an alternative deposition method to spin coating in the field of perovskite solar cells (PSCs) with the potential of scalable, low-cost, and no-waste manufacturing. In this study, the materials TiO₂, SrTiO₃, and SnO₂ were inkjet-printed as electron transport layers (ETLs), and the PSC performance based on these ETLs was optimized by adjusting the ink preparation methods and printing processes. For the mesoporous ETLs inkjet-printed from TiO₂ and SrTiO₃ nanoparticle inks, the selection of solvents for dispersing nanoparticles was found to be important and a cosolvent system is beneficial for the film formation. Meanwhile, to overcome the low current density and severe hysteresis in SrTiO₃-based devices, mixed mesoporous SrTiO₃/TiO₂ ETLs were also investigated. In addition, inkjet-printed SnO₂ thin films were fabricated by using a cosolvent system and the effect of the SnO₂ ink concentrations on the device performance was investigated. In comparison with PSCs based on TiO₂ and SrTiO₃ ETLs, the SnO₂-based devices offer an optimal power conversion efficiency (PCE) of 17.37% in combination with a low hysteresis. This work expands the range of suitable ETL materials for inkjet-printed PSCs and promotes the commercial applications of inkjet printing techniques in PSC manufacturing.

SUBMITTER: Lu D

PROVIDER: S-EPMC8704523 | biostudies-literature |

REPOSITORIES: biostudies-literature

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