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Redox switchable catalysis utilizing a fluorescent dye.


ABSTRACT: This report describes the implementation of a 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dye into the ligand framework of a Rh-based catalyst. The redox-active nature of the BODIPY dye is utilized to generate a catalyst that is capable of exhibiting redox-switchable catalytic behavior for the hydroboration of alkenes through a BODIPY-based reduction.

SUBMITTER: Thompson BL 

PROVIDER: S-EPMC6953248 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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Redox switchable catalysis utilizing a fluorescent dye.

Thompson Brena L BL   Simons Casey R CR   Heiden Zachariah M ZM  

Chemical communications (Cambridge, England) 20190901 76


This report describes the implementation of a 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dye into the ligand framework of a Rh-based catalyst. The redox-active nature of the BODIPY dye is utilized to generate a catalyst that is capable of exhibiting redox-switchable catalytic behavior for the hydroboration of alkenes through a BODIPY-based reduction. ...[more]

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