Ontology highlight
ABSTRACT:
SUBMITTER: Lenczyk C
PROVIDER: S-EPMC6972581 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20191209 72
The reactivity of a diruthenium tetrahydride complex towards three selected dihydroboranes was investigated. The use of [DurBH<sub>2</sub> ] (Dur=2,3,5,6-Me<sub>4</sub> C<sub>6</sub> H) and [(Me<sub>3</sub> Si)<sub>2</sub> NBH<sub>2</sub> ] led to the formation of bridging borylene complexes of the form [(Cp*RuH)<sub>2</sub> BR] (Cp*=C<sub>5</sub> Me<sub>5</sub> ; 1 a: R=Dur; 1 b: R=N(SiMe<sub>3</sub> )<sub>2</sub> ) through oxidative addition of the B-H bonds with concomitant hydrogen liberatio ...[more]