Ontology highlight
ABSTRACT:
SUBMITTER: Nicholson WI
PROVIDER: S-EPMC6972762 | biostudies-literature | 2020 Jan
REPOSITORIES: biostudies-literature
ChemSusChem 20191127 1
The ability to conduct N-heterocyclic carbene-catalysed acyl anion chemistry under ball-milling conditions is reported for the first time. This process has been exemplified through applications to intermolecular-benzoin, intramolecular-benzoin, intermolecular-Stetter and intramolecular-Stetter reactions including asymmetric examples and demonstrates that this mode of mechanistically complex organocatalytic reaction can operate under solvent-minimised conditions. ...[more]