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Chemoenzymatic Halocyclization of ?,?-Unsaturated Carboxylic Acids and Alcohols.

ABSTRACT: A chemoenzymatic method for the halocyclization of unsaturated alcohols and acids by using the robust V-dependent chloroperoxidase from Curvularia inaequalis (CiVCPO) as catalyst has been developed for the in situ generation of hypohalites. A broad range of halolactones and cyclic haloethers are formed with excellent performance of the biocatalyst.

SUBMITTER: Younes SHH 

PROVIDER: S-EPMC6973245 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Chemoenzymatic Halocyclization of γ,δ-Unsaturated Carboxylic Acids and Alcohols.

Younes Sabry H H SHH   Tieves Florian F   Lan Dongming D   Wang Yonghua Y   Süss Philipp P   Brundiek Henrike H   Wever Ron R   Hollmann Frank F  

ChemSusChem 20191022 1

A chemoenzymatic method for the halocyclization of unsaturated alcohols and acids by using the robust V-dependent chloroperoxidase from Curvularia inaequalis (CiVCPO) as catalyst has been developed for the in situ generation of hypohalites. A broad range of halolactones and cyclic haloethers are formed with excellent performance of the biocatalyst. ...[more]

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