An indenide-tethered N-heterocyclic stannylene.
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ABSTRACT: The structure of (?-1?N:2(?2),?2 N,N?-(2-{[2,6-bis(propan-2-yl)phenyl]azanidyl}ethyl)[2-(1H-inden-1-yl)ethyl]azanido)(1,4,7,10,13,16-hexaoxacyclooctadecane-1?6 O)lithiumtin, [LiSn(C8H16O4)(C25H31N2)], at 100?K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn interacts in an ?2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclopentadienyl ligands and their derivatives.
SUBMITTER: Bischof T
PROVIDER: S-EPMC7001827 | biostudies-literature | 2020 Feb
REPOSITORIES: biostudies-literature
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