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An indenide-tethered N-heterocyclic stannylene.


ABSTRACT: The structure of (?-1?N:2(?2),?2 N,N?-(2-{[2,6-bis(propan-2-yl)phen­yl]aza­nid­yl}eth­yl)[2-(1H-inden-1-yl)eth­yl]aza­nido)(1,4,7,10,13,16-hexa­oxa­cyclo­octa­dec­ane-1?6 O)lithiumtin, [LiSn(C8H16O4)(C25H31N2)], at 100?K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn inter­acts in an ?2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclo­penta­dienyl ligands and their derivatives.

SUBMITTER: Bischof T 

PROVIDER: S-EPMC7001827 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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