Tuning radical interactions in trisradical tricationic complexes by varying host-cavity sizes.

ABSTRACT: Although host-guest pairing interactions between bisradical dicationic cyclobis(paraquat-p-phenylene) (BB2(?+) ) and the bipyridinium radical cation (BIPY?+ ) have been studied extensively, host molecules other than BB2(?+) are few and far between. Herein, four bisradical dicationic cyclophanes with tunable cavity sizes are investigated as new bisradical dicationic hosts for accommodating the methyl viologen radical cation (MV?+ ) to form trisradical tricationic complexes. The structure-property relationships between cavity sizes and binding affinities have been established by comprehensive solution and solid-state characterizations as well as DFT calculations. The association constants of the four new trisradical tricationic complexes are found to range between 7400 and 170?000 M-1, with the strongest one being 4.3 times higher than that for [MV?BB]3(?+) . The facile accessibility and tunable stability of these new trisradical tricationic complexes make them attractive redox-controlled recognition motifs for further use in supramolecular chemistry and mechanostereochemistry.

SUBMITTER: Cai K 

PROVIDER: S-EPMC7012021 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature