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TiO2 Modified with Organic Acids for the Decomposition of Chlorfenvinphos under the Influence of Visible Light: Activity, Performance, Adsorption, and Kinetics.

ABSTRACT: Photocatalytic decomposition of chlorfenvinphos (CFVP) in the presence of titanium dioxide (TiO2) modified with organic acids: pyruvic (PA) and succinic (SA) under the visible light radiation has been studied. The following tests were examined: dose of photocatalysts, adsorption time, pH of the model solution, deactivation of catalysts, the role of oxygen, identification of free radicals for the CFVP decomposition, Langmuir-Hinshelwood kinetics. The synthesized materials were characterized by Scanning Electron Microscopy (SEM) and UV-Vis. At 10 wt.% of acid (90:10) decomposition of chlorfenvinphos was the most effective in the following conditions: dose of catalyst 50.0 mg/L, time of adsorption = 20 min, pH of model solution = 3.0. Under these conditions the order of photocatalyst efficiency has been proposed: TiO2/PA/90:10 > TiO2/SA/90:10 > TiO2 with the removal degree of 85, 72 and 48%. The mathematically calculated half-life at this conditions was 27.0 min and 39.0 min for TiO2/PA/90:10 and TiO2/SA/90:10 respectively, compared to 98 min for pure TiO2. It has been determined that the O2- radicals and holes (h+) are the main reactive species involved in the photodegradation of chlorfenvinphos. The results of this study showed that method may be an interesting alternative for the treatment of chlorfenvinphos contaminated wastewater.

SUBMITTER: Zawadzki P

PROVIDER: S-EPMC7013527 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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TiO<sub>2</sub> Modified with Organic Acids for the Decomposition of Chlorfenvinphos under the Influence of Visible Light: Activity, Performance, Adsorption, and Kinetics.

Zawadzki Piotr P

Materials (Basel, Switzerland) 20200108 2

Photocatalytic decomposition of chlorfenvinphos (CFVP) in the presence of titanium dioxide (TiO<sub>2</sub>) modified with organic acids: pyruvic (PA) and succinic (SA) under the visible light radiation has been studied. The following tests were examined: dose of photocatalysts, adsorption time, pH of the model solution, deactivation of catalysts, the role of oxygen, identification of free radicals for the CFVP decomposition, Langmuir-Hinshelwood kinetics. The synthesized materials were characte ...[more]

PMID: 31936390

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Project description:Commercial titania photocatalysts were modified with silver and gold by photodeposition, and characterized by diffuse reflectance spectroscopy (DRS), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning transmission electron microscopy (STEM). It was found that silver co-existed in zero valent (core) and oxidized (shell) forms, whereas gold was mainly zero valent. The obtained noble metal-modified samples were examined with regard to antibacterial (Escherichia coli (E. coli)) and antifungal (Aspergillus niger (A. niger), Aspergillus melleus (A. melleus), Penicillium chrysogenum (P. chrysogenum), Candida albicans (C. albicans)) activity under visible-light irradiation and in the dark using disk diffusion, suspension, colony growth ("poisoned food") and sporulation methods. It was found that silver-modified titania, besides remarkably high antibacterial activity (inhibition of bacterial proliferation), could also decompose bacterial cells under visible-light irradiation, possibly due to an enhanced generation of reactive oxygen species and the intrinsic properties of silver. Gold-modified samples were almost inactive against bacteria in the dark, whereas significant bactericidal effect under visible-light irradiation suggested that the mechanism of bacteria inactivation was initiated by plasmonic excitation of titania by localized surface plasmon resonance of gold. The antifungal activity tests showed efficient suppression of mycelium growth by bare titania, and suppression of mycotoxin generation and sporulation by gold-modified titania. Although, the growth of fungi was hardly inhibited through disc diffusion (inhibition zones around discs), it indicates that gold does not penetrate into the media, and thus, a good stability of plasmonic photocatalysts has been confirmed. In summary, it was found that silver-modified titania showed superior antibacterial activity, whereas gold-modified samples were very active against fungi, suggesting that bimetallic photocatalysts containing both gold and silver should exhibit excellent antimicrobial properties.

Dataset Information

TiO2 Modified with Organic Acids for the Decomposition of Chlorfenvinphos under the Influence of Visible Light: Activity, Performance, Adsorption, and Kinetics.

Publications

TiO<sub>2</sub> Modified with Organic Acids for the Decomposition of Chlorfenvinphos under the Influence of Visible Light: Activity, Performance, Adsorption, and Kinetics.

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