Ontology highlight
ABSTRACT:
SUBMITTER: Lindley BM
PROVIDER: S-EPMC7017868 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
Chemical science 20190820 40
A C-H bond activation strategy based on electrochemical activation of a metal hydride is introduced. Electrochemical oxidation of ( <sup><i>t</i>Bu<sub>4</sub></sup> PCP)IrH<sub>4</sub> ( <sup><i>t</i>Bu<sub>4</sub></sup> PCP is [1,3-( <sup><i>t</i></sup> Bu<sub>2</sub>PCH<sub>2</sub>)-C<sub>6</sub>H<sub>3</sub>]<sup>-</sup>) in the presence of pyridine derivatives generates cationic Ir hydride complexes of the type [( <sup><i>t</i>Bu<sub>4</sub></sup> PCP)IrH(L)]<sup>+</sup> (where L = pyridine ...[more]