Ontology highlight
ABSTRACT:
SUBMITTER: Pecak J
PROVIDER: S-EPMC7842137 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
Pecak Jan J Fleissner Sarah S Veiros Luis F LF Pittenauer Ernst E Stöger Berthold B Kirchner Karl K
Organometallics 20210105 2
The synthesis, characterization, and catalytic activity of low-spin {CoNO}<sup>8</sup> pincer complexes of the type [Co(PCP)(NO)(H)] are described. These compounds are obtained either by reacting [Co(PCP)(κ<sup>2</sup>-BH<sub>4</sub>)] with NO and Et<sub>3</sub>N or, alternatively, by reacting [Co(PCP)(NO)]<sup>+</sup> with boranes, such as NH<sub>3</sub>·BH<sub>3</sub> in solution. The five-coordinate, diamagnetic Co(III) complex [Co(PCP<sup>NMe</sup>-<i>i</i>Pr)(NO)(H)] was found to be the act ...[more]