Dataset Information

Comparative Studies on Polyurethane Composites Filled with Polyaniline and Graphene for DLP-Type 3D Printing.

ABSTRACT: Digital light processing (DLP)-type 3D printing ensures several advantages, such as an easy solution process, a short printing time, high-quality printing, and selective light curing. Furthermore, polyurethane (PU) is among the promising candidates for 3D printing because of its wide range of applications. This work reports comparative studies on the fabrication and optimization of PU composites using a polyaniline (PANI) nanomaterial and a graphene sheet (GS) for DLP-type 3D printing. The morphologies and dispersion of the printed PU composites were studied by field emission scanning electron microscope (FE-SEM) images. Bonding structures in the PU composites were investigated by Fourier-transform infrared (FT-IR) spectroscopy. As-prepared PU/PANI and PU/GS composites with different filler contents were successfully printed into sculptures with different sizes and shapes. The PU/PANI and PU/GS composites exhibit the improved sheet resistance, which is up to 8.57 × 104 times (1.19 × 106 ohm/sq) lower and 1.27 × 105 times (8.05 × 105 ohm/sq) lower, respectively, than the pristine PU (1.02 × 1011 ohm/sq). Moreover, the PU/PANI and PU/GS composites demonstrate 1.41 times (44.5 MPa) higher and 2.19 times (69.3 MPa) higher tensile strengths compared with the pristine PU (31.6 MPa). This work suggests the potential uses of highly conductive PU composites for DLP-type 3D printing.

SUBMITTER: Joo H

PROVIDER: S-EPMC7023528 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Comparative Studies on Polyurethane Composites Filled with Polyaniline and Graphene for DLP-Type 3D Printing.

Joo Hyeonseo H Cho Sunghun S

Polymers 20200102 1

Digital light processing (DLP)-type 3D printing ensures several advantages, such as an easy solution process, a short printing time, high-quality printing, and selective light curing. Furthermore, polyurethane (PU) is among the promising candidates for 3D printing because of its wide range of applications. This work reports comparative studies on the fabrication and optimization of PU composites using a polyaniline (PANI) nanomaterial and a graphene sheet (GS) for DLP-type 3D printing. The morph ...[more]

PMID: 31906536

Similar Datasets

Project description:Three-dimensional printing is regarded as a future-oriented additive manufacturing technology that is making significant contributions to the field of polymer processing. Among the 3D printing methods, the DLP (digital light processing) technique has attracted great interest because it requires a short printing time and enables high-quality printing through selective light curing of polymeric materials. In this study, we report a fabrication method for ABS-like resin composites containing polyaniline (PANI) nanofibers and graphene flakes suitable for DLP 3D printing. As-prepared ABS-like resin composite inks employing PANI nanofibers and graphene flakes as co-fillers were successfully printed, obtaining highly conductive and mechanically robust products with the desired shapes and different sizes through DLP 3D printing. The sheet resistance of the 3D-printed composites was reduced from 2.50 × 1015 ohm/sq (sheet resistance of pristine ABS-like resin) to 1.61 × 106 ohm/sq by adding 3.0 wt.% of PANI nanofibers and 1.5 wt.% of graphene flakes. Furthermore, the AP3.0G1.5 sample (the 3D-printed composite containing 3.0 wt.% of PANI nanofibers and 1.5 wt.% of graphene flakes) exhibited 2.63 times (22.23 MPa) higher tensile strength, 1.47 times (553.8 MPa) higher Young's modulus, and 5.07 times (25.83%) higher elongation at break values compared to the pristine ABS-like resin with a tensile strength of 8.46 MPa, a Young's modulus of 376.6 MPa, and an elongation at break of 5.09%. Our work suggests the potential use of highly conductive and mechanically robust ABS-like resin composites in the 3D printing industry. This article not only provides optimized DLP 3D printing conditions for the ABS-like resin, which has both the advantages of the ABS resin and the advantages of a thermoplastic elastomer (TPE), but also presents the effective manufacturing process of ABS-like resin composites with significantly improved conductivity and mechanical properties.

Dataset Information

Comparative Studies on Polyurethane Composites Filled with Polyaniline and Graphene for DLP-Type 3D Printing.

Publications

Comparative Studies on Polyurethane Composites Filled with Polyaniline and Graphene for DLP-Type 3D Printing.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets