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Tunable Aryl Imidazolium Recyclable Ionic Liquid with Dual Bronsted-Lewis Acid as Green Catalyst for Friedel-Crafts Acylation and Thioesterification.

ABSTRACT: Unique tunable aryl imidazolium ionic liquids successfully catalyzed Friedel-Crafts acylation and thioesterification in sealed tubes. These reactions can form a C-C bond and a C-S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excellent yields while retaining their catalytic activities for recycling.

SUBMITTER: Lin YJ

PROVIDER: S-EPMC7024267 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Tunable Aryl Imidazolium Recyclable Ionic Liquid with Dual Brønsted-Lewis Acid as Green Catalyst for Friedel-Crafts Acylation and Thioesterification.

Lin Yi-Jyun YJ Wu Yao-Peng YP Thul Mayur M Hung Ming-Wei MW Chou Shih-Huan SH Chen Wen-Tin WT Lin Wesley W Lin Michelle M Reddy Daggula Mallikarjuna DM Wu Hsin-Ru HR Ho Wen-Yueh WY Luo Shun-Yuan SY

Molecules (Basel, Switzerland) 20200115 2

Unique tunable aryl imidazolium ionic liquids successfully catalyzed Friedel-Crafts acylation and thioesterification in sealed tubes. These reactions can form a C-C bond and a C-S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excellent yields while retaining their catalytic activities for recycling. ...[more]

PMID: 31952217

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