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Tunable Aryl Imidazolium Recyclable Ionic Liquid with Dual Bronsted-Lewis Acid as Green Catalyst for Friedel-Crafts Acylation and Thioesterification.


ABSTRACT: Unique tunable aryl imidazolium ionic liquids successfully catalyzed Friedel-Crafts acylation and thioesterification in sealed tubes. These reactions can form a C-C bond and a C-S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excellent yields while retaining their catalytic activities for recycling.

SUBMITTER: Lin YJ 

PROVIDER: S-EPMC7024267 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Tunable Aryl Imidazolium Recyclable Ionic Liquid with Dual Brønsted-Lewis Acid as Green Catalyst for Friedel-Crafts Acylation and Thioesterification.

Lin Yi-Jyun YJ   Wu Yao-Peng YP   Thul Mayur M   Hung Ming-Wei MW   Chou Shih-Huan SH   Chen Wen-Tin WT   Lin Wesley W   Lin Michelle M   Reddy Daggula Mallikarjuna DM   Wu Hsin-Ru HR   Ho Wen-Yueh WY   Luo Shun-Yuan SY  

Molecules (Basel, Switzerland) 20200115 2


Unique tunable aryl imidazolium ionic liquids successfully catalyzed Friedel-Crafts acylation and thioesterification in sealed tubes. These reactions can form a C-C bond and a C-S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excellent yields while retaining their catalytic activities for recycling. ...[more]

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