Unknown

Dataset Information

0

Cathode Properties of Na3FePO4CO3 Prepared by the Mechanical Ball Milling Method for Na-ion Batteries.

ABSTRACT: The carbonophosphate Na3FePO4CO3 was synthesized by the mechanical ball milling method for the first time. The composition of the obtained sample with a higher amount of Fe2+ was Na2.66Fe2+0.66Fe3+0.34PO4CO3 as confirmed by Mössbauer analysis, owing to the good airtight properties of this method. The obtained samples in an organic electrolyte delivered an initial discharge capacity of 124 mAh/g at room temperature, and a larger discharge capacity of 159 mAh/g (1.66 Na+/mole) at 60?°C. With 17?m NaClO4 aqueous electrolyte, a discharge capacity of 161 mAh/g (1.69 Na+/mole) was delivered because of the high ionic conductivity of the concentrated aqueous electrolyte. During the charge-discharge process, the formation of Fe4+ after charging up to 4.5?V and the return of Fe2+ after discharging down to 1.5?V were detected by ex-situ X-ray absorption near edge structure (XANES) analysis.

SUBMITTER: Xie B 

PROVIDER: S-EPMC7039986 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Cathode Properties of Na<sub>3</sub>FePO<sub>4</sub>CO<sub>3</sub> Prepared by the Mechanical Ball Milling Method for Na-ion Batteries.

Xie Baowei B   Sakamoto Ryo R   Kitajou Ayuko A   Nakamoto Kosuke K   Zhao Liwei L   Okada Shigeto S   Fujita Yuki Y   Oka Nobuto N   Nishida Tetsuaki T   Kobayashi Wataru W   Okada Masaki M   Takahara Toshiya T  

Scientific reports 20200224 1

The carbonophosphate Na<sub>3</sub>FePO<sub>4</sub>CO<sub>3</sub> was synthesized by the mechanical ball milling method for the first time. The composition of the obtained sample with a higher amount of Fe<sup>2+</sup> was Na<sub>2.66</sub>Fe<sup>2+</sup><sub>0.66</sub>Fe<sup>3+</sup><sub>0.34</sub>PO<sub>4</sub>CO<sub>3</sub> as confirmed by Mössbauer analysis, owing to the good airtight properties of this method. The obtained samples in an organic electrolyte delivered an initial discharge cap  ...[more]

Similar Datasets

Unknown Off-stoichiometric Na<sub>3-3<i>x</i></sub> V<sub>2+<i>x</i></sub> (PO<sub>4</sub>)<sub>3</sub>/C nanocomposites as cathode materials for high-performance sodium-ion batteries prepared by high-energy ball milling.
| S-EPMC9080805 | biostudies-literature
Unknown Caffeine-Derived Noble Carbons as Ball Milling-Resistant Cathode Materials for Lithium-Ion Capacitors.
| S-EPMC8251692 | biostudies-literature
Unknown Insertion compounds and composites made by ball milling for advanced sodium-ion batteries.
| S-EPMC4735632 | biostudies-literature
Unknown Realizing a High-Performance Na-Storage Cathode by Tailoring Ultrasmall Na<sub>2</sub>FePO<sub>4</sub>F Nanoparticles with Facilitated Reaction Kinetics.
| S-EPMC6662290 | biostudies-literature
Unknown Ab Initio Study of AMBO<sub>3</sub> (A = Li, Na and M = Mn, Fe, Co, Ni) as Cathode Materials for Li-Ion and Na-Ion Batteries.
| S-EPMC7178776 | biostudies-literature
Unknown Detailed investigation of Na2.24FePO4CO3 as a cathode material for Na-ion batteries.
| S-EPMC3942702 | biostudies-literature
Unknown Pure Single-Crystalline Na<sub>1.1</sub>V<sub>3</sub>O<sub>7.9</sub> Nanobelts as Superior Cathode Materials for Rechargeable Sodium-Ion Batteries.
| S-EPMC5115286 | biostudies-literature
Unknown Simply Prepared Magnesium Vanadium Oxides as Cathode Materials for Rechargeable Aqueous Magnesium Ion Batteries.
| S-EPMC9412870 | biostudies-literature
Unknown Towards a High-Power Si@graphite Anode for Lithium Ion Batteries through a Wet Ball Milling Process.
| S-EPMC7321121 | biostudies-literature
Unknown Synthesis and Characterizations of Na<sub>4</sub>MnCr(PO<sub>4</sub>)<sub>3</sub>/rGO as NASICON-Type Cathode Materials for Sodium-ion Batteries.
| S-EPMC9570804 | biostudies-literature